I am in a similar situation with a set of 6 spoke magnesium marchesini's and have been doing a lot of research regarding the same question.
You can pay to have Non Destructive Tests performed on them to determine their internal and external structural integrity, but unless you know someone in the in the aerospace field it may cost you more than what you paid for the used wheels. The 2 types of tests that I have learned about for wheels are eddy current testing and x-ray, both costing over $450 min.
As far as everything else, there are motorcycle frame/wheel service shops around the country that can check your wheels for straightness, check & replace bearings and straighten your wheels if need be.
I'll be taking mine to dr. john's frame service in anaheim as soon as I have the $$$ for the all the services Im going to have performed.
Dr. John's Motorcycle Frame Straightening
*don't be fooled by his chopperesque website, he is the top wheel guy for most US pro roadracing teams.